Oh, and they remembered that they'd been richer before they met him
As enthusiastically as I have proselytized about Terry Pratchett's Going Postal (2004) for the last several years—I now find myself telling people that it's my favorite Discworld novel—I was still somewhat surprised to discover that there is an adaptation of it in the works. I'm not disappointed, I'm just not used to anyone having the same favorite anything as me. But unless I hear reason otherwise, I am really going to look forward to it. IMDb tells me that its con-man protagonist, Moist von Lipwig, is going be played by Richard Coyle. Otherwise known (at least to me) as Jeff, from Coupling. And that really has the potential to be awesome.

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I am one of the readers who by far prefers the latter, so I have no idea where I would suggest you start, but I imagine order of publication might serve as well as anything else.
I don't mind complex social satire, as long as I'm not adrift in a book that assumes having read previous books. I mostly read The Colour of Magic first because somebody said "You should read this" and gave me a copy.
I suppose I'll try order of publication, then. Thanks!