All cheap and debonair
Talk to me about supporting characters. When you're supposed to fall for the heroine, and instead it's the second spear-carrier from the left who turns out to have the thorniest moral dilemma or the most fascinating backstory. This happens to me all the time; I can't be the only one. So who are your scene-stealers? Movies, books, operas—your own work—which character roles do you remember long after you've forgotten who played the protagonist?
(This post brought to you courtesy of Eleanor Cameron and L.M. Montgomery.)
(This post brought to you courtesy of Eleanor Cameron and L.M. Montgomery.)

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Maybe Kikuchiyo in Seven Samurai. Definitely Lady Kaede in Ran.
The trouble is, when I try to think of any such character, it's easy to see how they would become less interesting if more attention was given to them.
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Unfortunately, she is so awful, so truly fucking flat and boring, and the plot is so lousy that I can't possibly recommend the books. It's a damn shame.
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Oh, I know. Reepicheep. Totally steals the show.
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Silk (from the Belgariad/Malloreon),
Bester (Babylon 5 -- Londo and G'kar seem too main cast to count),
Harvey (Farscape)
Saffron (Firefly)
I may think of more and double post. But that's a start :)
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I can probably think of a few more, but those are ones that immediately come to mind.
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Badger, from The Wind in the Willows.
From my own work, I think Violeta stuck with me far longer than I thought she would. Sticks. Muh. Very sleepy.
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That said: Inigo and Fezig from Princess Bride.
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From the books I can remember, we have the Fool in Hobb's Farseer series, Mr. Flay from Gormenghast, Hermione and Ron (and the rest of the Weasley Family, esp. Fred and George) in Potter. Those are all obvious and easy.
For movies I draw a blank. Most of them I have seen recently are pretty sparse with characters, though I would have rather seen the sisters in The Descent escape than Juno or Ms. Crazy-covered-in-blood, even though she looked all cool and haggish.
Because I played a lot of video games the last couple of weeks, Auron, who was in Kingdom Hearts 2 and (apparently) Final Fantasy 10 was an interesting seeming dead fellow.
Finally, in my own work, my dearest darling that I had to murder out of Blue Vervain Quoholloi, the graveyard goblin, who could do almost anything you told him to do, up to and including get smarter and was every bit the hero the rest of his companions really were not.
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From Laurel K. Hamilton's series (which I don't recommend, though it might be fun to watch your head exploding in horror), Asher.
From Robert Jordan, Min.
Jack from The Blue Sword. As far as I'm concerned, the only interesting hero from Robin McKinley's Damar books was Tor. Luth and Corlath had their points, I suppose, but I never appreciated them as much as I was supposed to.
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Now, I have to think about your question a bit longer, think about what side characters I fell for (well, obviously, in the book I'd just read, the antagonist is the one who stole my heart). But I'm sure there's more. So, who came to mind for you?
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--Crack from Martha Wells' excellent "Death of a Necromancer"
--Jessica Sorrow from Simon Green's Nightside books
--Bobbi Yee from Elizabeth Bear's "Hammered"
TV:
The only one who springs readily to mind is Angelo from "The Pretender". C'mon! He lived in the crawlspace! There had to be a great backstory there!
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I am more interested in virtually any non-Fellowship character in LOTR than in the Fellowship ones. I liked Cordelia, Giles, and Anya best on Buffy. One of my favorite things about Madeleine L'Engle's books is the way her cast of supporting characters keep wandering in and out of multiple books. Virtually every Agatha Christie had more interesting supporting characters than the detective(s), but I think that was usually intentional. And I have to admit, I sort of wonder what became of Catherine Darcy and Charlotte Collins, but not enough to read godawful contemporary continuations of Pride and Prejudice.
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scene stealers
and Tars Tarkus, the Thark from the Martian novels of Edgar Rice Burroughs.
Rick